HAZMAT Placards for EMS: A Quick Reference

How to read DOT hazard class placards from a safe distance, ERG lookup basics, and the EMS role at HAZMAT scenes.

October 30, 2026 · 7 min read

EMS at a HAZMAT scene has one job before anything else: don't become a patient. Read the placard from upwind, uphill, upstream — and let hazmat-trained crews do decon.

The nine hazard classes

  • 1 — Explosives (orange)
  • 2 — Gases (red flammable, green non-flammable, white poison)
  • 3 — Flammable liquids (red)
  • 4 — Flammable solids (red/white stripes)
  • 5 — Oxidizers & organic peroxides (yellow)
  • 6 — Poisons & infectious (white)
  • 7 — Radioactive (yellow/white)
  • 8 — Corrosives (white/black)
  • 9 — Miscellaneous (white/black stripes)

The 4-digit UN number

The number in the middle of the placard is the UN identifier. Look it up in the Emergency Response Guide (ERG) — the orange section gives isolation and protective distances.

EMS role at the scene

  • Stage upwind, uphill, and outside the isolation zone from ERG.
  • Do not enter the hot or warm zone without proper PPE and training.
  • Treat patients only after gross decon is complete.
  • Notify the receiving ED early so they can prep.

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